- alkyl halide
- allylic
- carbanion
- delocalized
- Gilman reagent (LiR2Cu)
- Grignard reagent (RMgX)
- organohalide
- organometallic
Summary of Reactions
No stereochemistry is implied unless specifically indicated with wedged, solid, and dashed lines.
- Preparation of alkyl halides
- From alkenes by allylic bromination (Section 10.3)
- From alcohols (Section 10.5)
- Reaction with HX
- Reaction of 1° and 2° alcohols with SOCl2
- Reaction of 1° and 2° alcohols with PBr3
- Reaction of 1° and 2° alcohols with HF–pyridine
- Reactions of alkyl halides
- Formation of Grignard (organomagnesium) reagents (Section 10.6)
- Organometallic coupling (Section 10.7)
- Diorganocopper reaction
- Palladium-catalyzed Suzuki–Miyaura reaction