• alkyl halide
  • allylic
  • carbanion
  • delocalized
  • Gilman reagent (LiR2Cu)
  • Grignard reagent (RMgX)
  • organohalide
  • organometallic

Summary of Reactions

No stereochemistry is implied unless specifically indicated with wedged, solid, and dashed lines.

  • Preparation of alkyl halides
  • From alkenes by allylic bromination (Section 10.3)

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  • From alcohols (Section 10.5)
  • Reaction with HX

  • Reaction of 1° and 2° alcohols with SOCl2

  • Reaction of 1° and 2° alcohols with PBr3

  • Reaction of 1° and 2° alcohols with HF–pyridine

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  • Reactions of alkyl halides
  • Formation of Grignard (organomagnesium) reagents (Section 10.6)

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  • Organometallic coupling (Section 10.7)
  • Diorganocopper reaction

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  • Palladium-catalyzed Suzuki–Miyaura reaction

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