• acetylide anion
  • alkylation
  • alkyne
  • enol
  • Lindlar Catalyst
  • retrosynthetic
  • tautomer

Summary of Reactions

No stereochemistry is implied unless specifically indicated with wedged, solid, and dashed lines.

  • Preparation of alkynes
    • Dehydrohalogenation of vicinal dihalides (Section 9.2)

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    • Alkylation of acetylide anions (Section 9.8)

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  • Reactions of alkynes
    • Addition of HCl and HBr (Section 9.3)

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    • Addition of Cl2 and Br2 (Section 9.3)

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  • Hydration (Section 9.4)
    • Mercuric sulfate catalyzed

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    • Hydroboration–oxidation

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  • Reduction (Section 9.5)
    • Catalytic hydrogenation

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    • Lithium in liquid ammonia

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  • Conversion into acetylide anions (Section 9.7)

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