Key Terms

  • alkyl halide
  • allylic
  • carbanion
  • delocalized
  • Grignard reagent (RMgX)
  • organohalide
  • organometallic

Summary of Reactions 6

No stereochemistry is implied unless specifically indicated with wedged, solid, and dashed lines.

  1. Preparation of alkyl halides from Alcohols

Reaction with HX

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Reaction of 1° and 2° alcohols with SOCl2

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Reaction of 1° and 2° alcohols with PBr3

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Reaction of 1° and 2° alcohols with HF–pyridine

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2. Reactions of alkyl halides

Formation of Grignard (organomagnesium) reagents

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Fundamentals of Organic Chemistry-OpenStax Adaptation Copyright © by Kirsten Kramer and Cassandra Lilly is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License, except where otherwise noted.

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