Key Terms

  • alkylamine
  • amine
  • arylamine
  • azo compound (R–N=N–R′)
  • Curtius rearrangement
  • Gabriel amine synthesis
  • heterocyclic amine
  • Hofmann elimination reaction
  • Hofmann rearrangement
  • imide (O=C–N–C=O)
  • primary amine (RNH2)
  • quaternary ammonium salt
  • reductive amination
  • Sandmeyer reaction
  • secondary amine (R2NH)
  • tertiary amine (R3N)

Summary of Reactions 24 • Summary of Reactions 24 • Summary of Reactions

  • Synthesis of amines (Section 24.6)
  • Reduction of nitriles

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  • Reduction of amides

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  • Reduction of nitrobenzenes

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  • SN2 Alkylation of alkyl halides

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  • Gabriel amine synthesis

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  • Reduction of azides

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  • Reductive amination of aldehydes/ketones

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  • Hofmann rearrangement of amides

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  • Curtius rearrangement of acyl azides

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  • Reactions of amines
  • Alkylation with alkyl halides; see reaction 1(d)
  • Hofmann elimination (Section 24.7)

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  • Diazotization (Section 24.8)

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  • Reactions of arenediazonium salts (Section 24.8)
  • Nucleophilic substitutions

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  • Diazonium coupling

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