Key Terms

  • α-amino acids
  • α helix
  • backbone
  • β-pleated sheet
  • C-terminal amino acid
  • coenzyme
  • cofactor
  • denatured
  • Edman degradation
  • enzyme
  • fibrous proteins
  • globular proteins
  • isoelectric point (pI)
  • N-terminal amino acid
  • peptides
  • primary structure
  • proteins
  • quaternary structure
  • residues
  • secondary structure
  • side chain
  • tertiary structure
  • turnover number
  • zwitterion

Summary of Reactions 26 • Summary of Reactions 26 • Summary of Reactions

  • Amino acid synthesis (Section 26.3)
  • From α-bromo acids

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  • Diethyl acetamidomalonate synthesis

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  • Reductive amination of an α-keto acid

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  • Enantioselective synthesis

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  • Peptide sequencing by Edman degradation (Section 26.6)

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  • Peptide synthesis (Section 26.7)
  • Amine protection

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  • Carboxyl protection

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